From the official synopsis provided by FOX:
PENGUIN WANTS TO MAKE GOTHAM SAFE AGAIN ON AN ALL-NEW “GOTHAM” MONDAY, OCTOBER 10, ON FOX
Penguin gains power as he narrows in on the nomination for Mayor of Gotham. Meanwhile, Gordon turns Alice (guest star Naian Gonzalez Norvind) into the GCPD for the bounty. Also, Bruce and Alfred race to find Bruce’s doppleganger after learning he’s assumed Bruce’s identity in the all-new “Mad City: New Day Rising” episode of GOTHAM airing Monday, Oct. 10 (8:00-9:01 PM ET/PT) on FOX. (GTH-304) (TV-14 L, V)
Cast: Ben McKenzie as Detective James Gordon, Donal Logue as Harvey Bullock, David Mazouz as Bruce Wayne, Morena Baccarin as Leslie Thompkins, Sean Pertwee as Alfred, Robin Lord Taylor as Oswald Cobblepot/The Penguin, Erin Richards as Barbara Kean, Camren Bicondova as Selina Kyle/the future Catwoman, Cory Michael Smith as Edward Nygma/the future Riddler, Jessica Lucas as Tabitha Galavan, Chris Chalk as Lucius Fox, Drew Powell as Butch Gilzean, Maggie Geha as the future Poison Ivy, Michael Chiklis as Detective Nathaniel Barnes
Guest Cast: Naian Gonzalez Norvind as Alice Tetch, Leslie Hendrix as Kathryn
“Gotham” airs on Mondays at 8 PM ET on Fox; “New Day Rising” will arrive on October 10.